Question:

What is the difference in terms of molar masses of second and fourth members of homologous series?

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Consecutive homologues differ by CH2 (14 g/mol), so the 2nd and 4th differ by two CH2 units.
Updated On: Oct 1, 2026
  • \(12\)
  • \(24\)
  • \(28\)
  • \(36\)
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The Correct Option is C

Solution and Explanation

Step 1: Understanding the Concept:
A homologous series is a family of compounds in which each member differs from the next by one \(-\text{CH}_2-\) unit.

Step 2: Find the mass of one CH2 unit:
\(12 + 2(1) = 14\) g/mol.

Step 3: Count the steps:
From the second member to the fourth member, there are two steps (second to third, third to fourth). So two \(-\text{CH}_2-\) groups are added.

Step 4: Calculate the difference:
\(2 \times 14 = 28\) g/mol.

Step 5: Why the other options are wrong.
12 is the mass of one C atom only. 24 is two C atoms and ignores hydrogen. 36 would mean about three CH2 units counted with a wrong mass.

Final Answer:
The difference in molar mass is 28. \[ \boxed{\text{(C) }28} \]
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