Step 1: Recall the general formula of alkanes.
Alkanes follow the general molecular formula \(\mathrm{C_nH_{2n+2}}\). Each successive member of the homologous series differs by one \(\mathrm{CH_2}\) unit.
Step 2: Calculate the molar mass of the repeating unit.
The molar mass of one \(\mathrm{CH_2}\) unit is:
\[
12 + (2 \times 1) = 14 \, \text{g mol}^{-1}
\]
Step 3: Conclusion.
Hence, the difference in molar mass between any two neighbouring alkanes is \(14 \, \text{g mol}^{-1}\).