Natural rubber is soft and sticky at high temperature and hard at low temperature.
These are undesirable properties of natural rubber.
To improve these properties, natural rubber is heated with sulphur.
This process is called vulcanization.
During vulcanization, sulphur forms cross-links between polymer chains of rubber.
These sulphur cross-links make rubber stronger, more elastic, and more resistant to temperature changes.
Thus, the undesirable properties of natural rubber are overcome by heating it with sulphur.