Question:

The structure of Buna-S polymer is

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Buna-S is made from butadiene and styrene; therefore, its structure contains a phenyl group \((C_6H_5)\).
  • \(\left[-CH_2-CH=CH-CH_2-CH(C_6H_5)-CH_2-\right]_n\)
  • \(\left[-CH_2-CH=CH-CH_2-CH(CN)-CH_2-\right]_n\)
  • \(\left[-CH_2-C(Cl)=CH-CH_2-\right]_n\)
  • \(\left[-NH-CO-NH-CH_2-\right]_n\)
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The Correct Option is A

Solution and Explanation

Concept: Buna-S is a copolymer of butadiene and styrene.

Step 1:
Buna-S is also called styrene-butadiene rubber.

Step 2:
The monomers are: \[ CH_2=CH-CH=CH_2 \] which is butadiene, and \[ C_6H_5CH=CH_2 \] which is styrene.

Step 3:
Since styrene contains the phenyl group: \[ C_6H_5 \] the Buna-S polymer must contain \(C_6H_5\) as a side group.

Step 4:
Therefore, the correct repeating unit is: \[ \left[-CH_2-CH=CH-CH_2-CH(C_6H_5)-CH_2-\right]_n \] Hence, \[ \boxed{\left[-CH_2-CH=CH-CH_2-CH(C_6H_5)-CH_2-\right]_n} \]
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