Volume of 3%solution of sodium carbonate necessary to neutralise a litre of 0.1 N sulphuric acid is
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To calculate the volume required for neutralization, use the relation \( N_1 V_1 = N_2 V_2 \), where \( N_1 \) and \( V_1 \) are the normality and volume of one reactant, and \( N_2 \) and \( V_2 \) are those of the other.
Step 1: Use the neutralization equation.
The neutralization reaction between sodium carbonate and sulphuric acid is given by:
\[
\text{Na}_2 \text{CO}_3 + \text{H}_2 \text{SO}_4 \rightarrow \text{Na}_2 \text{SO}_4 + \text{CO}_2 + \text{H}_2 \text{O}
\]
The molar equivalents of sodium carbonate are equal to those of sulphuric acid. Using the normality and volume of sulphuric acid, calculate the volume of sodium carbonate solution required.
Step 2: Calculate the volume.
The required volume of sodium carbonate solution is calculated as 176.66 ml using the equivalence factor.
Final Answer:
\[
\boxed{176.66 \, \text{ml}}
\]