Under isothermal condition, two soap bubbles of radii \(r_1\) and \(r_2\) combine to form a single soap bubble of radius R. The surface tension of the soap solution is (P = outside pressure)
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Apply Boyle law to the total gas, using the excess pressure 4S/r inside a soap bubble.
Step 1: Pressures
Inside a soap bubble of radius \(r\) the pressure is \(P + \frac{4S}{r}\).
Step 2: Boyle law at constant temperature
Total \(PV\) before equals after:
\[ \left(P+\frac{4S}{r_1}\right)\frac43\pi r_1^3 + \left(P+\frac{4S}{r_2}\right)\frac43\pi r_2^3 = \left(P+\frac{4S}{R}\right)\frac43\pi R^3 \]