Step 1: Understanding the Question:
We are given the peak emission colors of two stars and must determine the mathematical relationship between their surface temperatures.
Step 2: Key Formula or Approach:
Wien's Displacement Law states that the peak emission wavelength ($\lambda_m$) of a black body is inversely proportional to its absolute surface temperature ($T$).
$$\lambda_m T = b \implies T \propto \frac{1}{\lambda_m}$$
Step 3: Detailed Explanation:
From Wien's Law, a hotter star will emit light with a shorter peak wavelength, and a cooler star will emit light with a longer peak wavelength.
Star P emits yellow light, and Star Q emits blue light.
In the visible light spectrum (VIBGYOR), the wavelength of yellow light ($\lambda_P$) is significantly longer than the wavelength of blue light ($\lambda_Q$).
Since $\lambda_P > \lambda_Q$, the inverse relationship dictates that the temperature of star P must be lower than the temperature of star Q.
Therefore, $T_P < T_Q$.
Step 4: Final Answer:
The relation between their temperatures is $T_P < T_Q$, matching option (D).