Step 1: Understanding the Concept:
A throw of two dice has 36 outcomes, and 6 of them are doublets. So \(p = \dfrac16\) and \(q = \dfrac56\) per throw. Four independent throws make a binomial experiment with \(n = 4\).
Step 2: Use the complement:
\[ P(\text{at least one}) = 1 - P(\text{none}) = 1 - \left(\frac56\right)^4 \]