Step 1: Understanding the problem.
In a standard deck of 52 playing cards, there are 4 queens. When two cards are drawn without replacement, we are asked to find the probability that both cards are queens.
Step 2: Probability calculation.
The total number of ways to select 2 cards from 52 is \( \binom{52}{2} = \frac{52 \times 51}{2} = 1326 \).
The number of ways to select 2 queens from 4 is \( \binom{4}{2} = \frac{4 \times 3}{2} = 6 \).
Thus, the probability that both cards are queens is:
\[
P(\text{both queens}) = \frac{6}{1326} = \frac{1}{221}.
\]
Step 3: Conclusion.
Therefore, the correct answer is option (A) \( \frac{1}{221} \).