Step 1: Understanding the Concept:
The electrostatic potential energy of a set of point charges is the sum, over every pair, of \(\dfrac{1}{4\pi\epsilon_0}\dfrac{q_iq_j}{r_{ij}}\).
Step 2: Key Formula or Approach:
In the figure, the charge \(Q\) is at the right-angle corner. The charge \(2q\) is on one leg at distance \(\sqrt2a\), and the charge \(q\) is on the other leg, also at distance \(\sqrt2a\). The two legs are equal, so the distance between \(2q\) and \(q\) is the hypotenuse, \(\sqrt{2}\times\sqrt2a = 2a\).
Step 3: Detailed Explanation:
\[ U = k\left[\frac{Q(2q)}{\sqrt2a} + \frac{Qq}{\sqrt2a} + \frac{(2q)(q)}{2a}\right] \]
\[ U = \frac{k}{a}\left[\frac{3Qq}{\sqrt2} + q^2\right] \]
Set \(U = 0\):
\[ \frac{3Qq}{\sqrt2} = -q^2 \Rightarrow Q = -\frac{\sqrt2}{3}\,q \]
The sign is negative, so \(Q\) attracts the other two charges and balances the repulsion between \(2q\) and \(q\). Option (A) \(-\tfrac{1}{2\sqrt3}q\) and (C) \(-\tfrac{\sqrt3}{2}q\) do not satisfy the equation, and (D) \(-\sqrt{\tfrac23}q\) is larger in magnitude by a factor \(\sqrt3\).
Final Answer:
\(Q = -\dfrac{\sqrt2}{3}q\), option (B).
\[ \boxed{-\frac{\sqrt2}{3}q \text{ (B)}} \]