First, find the moles of ethanol required: \[ \text{Moles of ethanol} = M \times V = 0.25\, \text{mol/L} \times 3\, \text{L} = 0.75\, \text{mol} \] Now, calculate the mass of ethanol: \[ \text{Mass} = \text{moles} \times \text{molar mass} = 0.75 \times 60 = 45\, \text{g} \] Using the density formula, find the volume: \[ \text{Volume} = \frac{{\text{Mass}}}{{\text{Density}}} = \frac{45}{0.36} = 125\, \text{mL} \] Thus, the required volume of ethanol is 125 mL.
The decreasing order of stability of the following carbocations is:
\( (i) \text{(CH}_3\text{)}_3\text{C}^+ \quad (ii) \text{(CH}_3\text{)}_2\text{C-CH}_2^+ \quad (iii) \text{CH}_3\text{CH}_2\text{-CH}_2^+ \)
Kepler's second law (law of areas) of planetary motion leads to law of conservation of