Step 1: Let \(\sin\theta=s\).
Given expression is
\[
\frac{3+2i\sin\theta}{1-2i\sin\theta}
\]
Let
\[
s=\sin\theta
\]
Then the expression becomes
\[
\frac{3+2is}{1-2is}
\]
Step 2: Rationalize the denominator.
Multiply numerator and denominator by the conjugate of the denominator:
\[
\frac{3+2is}{1-2is}\times \frac{1+2is}{1+2is}
\]
\[
=\frac{(3+2is)(1+2is)}{(1-2is)(1+2is)}
\]
Step 3: Simplify the numerator and denominator.
Numerator:
\[
(3+2is)(1+2is)
\]
\[
=3+6is+2is+4i^2s^2
\]
Since
\[
i^2=-1,
\]
we get
\[
3+8is-4s^2
\]
So the numerator is
\[
3-4s^2+8is
\]
Denominator:
\[
(1-2is)(1+2is)=1+4s^2
\]
Therefore,
\[
\frac{3+2is}{1-2is}
=
\frac{3-4s^2+8is}{1+4s^2}
\]
Step 4: Apply the condition for the expression to be real.
For the expression to be real, its imaginary part must be zero.
The imaginary part is
\[
\frac{8s}{1+4s^2}
\]
So,
\[
\frac{8s}{1+4s^2}=0
\]
Since
\[
1+4s^2\neq 0,
\]
we must have
\[
s=0
\]
Thus,
\[
\sin\theta=0
\]
Step 5: Find the values of \(\theta\).
We know that
\[
\sin\theta=0
\]
when
\[
\theta=n\pi,\quad n\in \mathbb{Z}
\]
Step 6: Final conclusion.
Therefore,
\[
\boxed{\theta=n\pi,\quad n\in \mathbb{Z}}
\]