Concept:
Each quantum number describes a different property of electron in an atom.
Step 1: Meaning of principal quantum number $n$.
$n$ tells the main shell and size (energy level) of orbital.
So:
$$n \rightarrow \text{Size of orbital}$$
Hence IV $\to$ b
Step 2: Meaning of azimuthal quantum number $l$.
$l$ determines subshell type ($s,p,d,f$) and orbital shape.
So:
$$l \rightarrow \text{Shape of orbital}$$
Hence III $\to$ a
Step 3: Meaning of magnetic quantum number $m_l$.
$m_l$ gives spatial orientation of orbital.
So:
$$m_l \rightarrow \text{Orientation of orbital}$$
Hence I $\to$ c
Step 4: Meaning of spin quantum number $m_s$.
$m_s$ gives spin direction of electron.
So:
$$m_s \rightarrow \text{Orientation of electron spin}$$
Hence II $\to$ d
Therefore correct matching is:
$$\text{I-c,\ II-d,\ III-a,\ IV-b}$$
Hence correct option is (B). :contentReference[oaicite:0]{index=0}