Step 1: Understanding the Concept
During germination, stored food in the endosperm must be broken down for the growing embryo.
Step 2: Role of gibberellin
After imbibition, the embryo releases gibberellin. It reaches the aleurone layer and switches on synthesis of hydrolytic enzymes such as \(\alpha\)-amylase and proteases.
Step 3: Result
These enzymes convert starch and proteins into soluble sugars and amino acids. Abscisic acid acts oppositely and keeps seeds dormant.
Final Answer:
Gibberellin is responsible for the synthesis of hydrolytic enzymes.
\[ \boxed{\text{(D) }\text{Gibberellin.}} \]