Step 1: Assign oxidation states.
In \( \text{Na}_2 \text{S}_4 \text{O}_6 \), sodium (Na) has an oxidation state of +1, and oxygen (O) has an oxidation state of -2. Let the oxidation state of sulfur (S) be \( x \).
Step 2: Solve for the oxidation state of sulfur.
The total charge on the molecule is zero, so:
\[
2(+1) + 4x + 6(-2) = 0
\]
Solving for \( x \), we get \( x = +5 \).
Final Answer:
\[
\boxed{+5}
\]