Step 1: Understanding the Concept
The wall of a microspore (pollen grain) has two layers, the outer exine and the inner intine.
Step 2: Composition
The exine is thick and made of sporopollenin, which resists high temperature, strong acids, alkalis and enzymes.
The thin intine is made of cellulose and pectin.
Step 3: Conclusion
The outer thick layer is made of sporopollenin.
Final Answer:
The outer layer is made of sporopollenin.
\[ \boxed{\text{(C) }\text{sporopollenin}} \]