Step 1: Understanding the Concept:
Hemoglobin is a protein with a quaternary structure.
It consists of multiple polypeptide chains.
Step 2: Key Formula or Approach:
No specific formula.
Need to know the structure of hemoglobin.
Step 3: Detailed Explanation:
Hemoglobin is a tetramer.
It consists of four polypeptide chains.
In adult hemoglobin (HbA), it has two \(\alpha\)-chains and two \(\beta\)-chains.
Thus, the number of polypeptide chains is 4.
Step 4: Final Answer:
Hemoglobin has 4 polypeptide chains.
Hence, the correct option is (A).