Step 1: Concept
Acidity of hydrocarbons depends on the s-character of the carbon atom.
Step 2: Meaning
Terminal alkynes ($sp$ hybridized) have the highest s-character (50%).
Step 3: Analysis
Propyne is a terminal alkyne with a hydrogen attached to an $sp$ carbon, making it more acidic than alkanes or alkenes.
Step 4: Conclusion
Hence, the correct answer is propyne.
Final Answer: (D)