Step 1: Relation between half-life and decay constant
For a first-order reaction, the half-life is related to the decay constant by:
\( t_{1/2} = \frac{\ln 2}{\lambda} \)
Step 2: Substitute given value
Given:
\( t_{1/2} = 3 \, \text{min} \)
So,
\[
\lambda = \frac{\ln 2}{3}
\]
\[
\lambda = \frac{0.693}{3}
\]
\[
\lambda = 0.231 \, \text{min}^{-1}
\]
Final Answer:
\( \lambda = 0.231 \, \text{min}^{-1} \)