The slag in the blast furnace is formed by the reaction between calcium oxide (\( CaO \)) and silicon dioxide (\( SiO_2 \)), forming calcium silicate. This is the key reaction that forms the slag.
Step 2: Conclusion.
The reaction that forms the slag is \( CaO(s) + SiO_2(s) \rightarrow CaSiO_3 (s) \), corresponding to option (b).