Question:

The crystalline structure of NaCl is

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Rock salt structure: FCC of Cl\(^-\) with Na\(^+\) in all octahedral holes.
Updated On: Apr 20, 2026
  • hexagonal close packing
  • face centred cubic
  • square planar
  • body centred cubic
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The Correct Option is B

Solution and Explanation

Step 1: Understanding the Concept:
NaCl has a rock salt structure.

Step 2: Detailed Explanation:
NaCl crystallizes in a face-centred cubic (FCC) lattice. Cl\(^-\) ions form an FCC arrangement, and Na\(^+\) ions occupy all octahedral voids. Coordination number is 6:6.

Step 3: Final Answer:
Face centred cubic
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