Question:

The correct increasing order of number of electrons around the central atom in the following molecules is

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Count total electrons around central atom = 2 × (bond pairs + lone pairs).
Updated On: Apr 24, 2026
  • $SF_6<SCl_2<PF_5$
  • $SCl_2<PF_5<SF_6$
  • $PF_5<SCl_2<SF_6$
  • $SCl_2<SF_6<PF_5$
  • $PF_5<SF_6<SCl_2$
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The Correct Option is B

Solution and Explanation

Concept: Chemistry - Valence Shell Electron Pair Repulsion (VSEPR).
Step 1: Count electrons around central atom. * $SCl_2$: Sulfur has 2 bond pairs + 2 lone pairs = 4 pairs = 8 electrons * $PF_5$: Phosphorus has 5 bond pairs = 10 electrons * $SF_6$: Sulfur has 6 bond pairs = 12 electrons
Step 2: Arrange in increasing order. [ 8<10<12 ] So, [ SCl_2<PF_5<SF_6 ]
Step 3: Final answer. [ \boxed{SCl_2<PF_5<SF_6} ]
Hence, correct option is (B).
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