Step 1: Understanding the Concept:
Metallic character decreases across a period (left to right) and increases down a group (top to bottom) in the periodic table.
Step 2: Detailed Explanation:
1. Elements involved: Na ($Z=11$, Gp 1), Mg ($Z=12$, Gp 2), Be ($Z=4$, Gp 2), Si ($Z=14$, Gp 14), P ($Z=15$, Gp 15).
2. Group 1 metals (Na) are more metallic than Group 2 (Mg, Be).
3. In Group 2, Mg (higher period) is more metallic than Be.
4. Si and P are non-metals/metalloids in higher groups (14 and 15), so they have lower metallic character.
5. P (Group 15) is further right than Si (Group 14), making it the least metallic.
Ranking: P (Least) $<$ Si $<$ Be $<$ Mg $<$ Na (Most).
Step 3: Final Answer:
The correct order is P $<$ Si $<$ Be $<$ Mg $<$ Na.