In a semiconductor, conductivity is given by: \[ \sigma = n e \tau \] Where: - \( n \) is the number density of free charge carriers, - \( e \) is the charge of the electron, - \( \tau \) is the relaxation time. As the temperature increases, the number density of free carriers \( n \) increases due to the increased excitation of electrons from the valence band to the conduction band.
However, the relaxation time \( \tau \) typically decreases as temperature increases because higher temperatures cause more collisions of charge carriers, leading to more scattering. The net effect is that the increase in number density dominates, causing an overall increase in conductivity.
Thus, the correct answer is that the relaxation time increases with temperature, but the increase in number density is the primary reason for the increase in conductivity.

200 ml of an aqueous solution contains 3.6 g of Glucose and 1.2 g of Urea maintained at a temperature equal to 27$^{\circ}$C. What is the Osmotic pressure of the solution in atmosphere units?
Given Data R = 0.082 L atm K$^{-1}$ mol$^{-1}$
Molecular Formula: Glucose = C$_6$H$_{12}$O$_6$, Urea = NH$_2$CONH$_2$