Question:

The compound with the lowest pKa value is

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Acidity: p-nitrophenol $>$ phenol $>$ alcohols.
Updated On: Apr 27, 2026
  • ethanol
  • phenol
  • p-nitrophenol
  • o-cresol
  • p-cresol
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The Correct Option is C

Solution and Explanation

Step 1: Concept
Lower $pK_a$ value indicates higher acidity.

Step 2: Meaning

Electron-withdrawing groups (like $-NO_2$) increase the acidity of phenols.

Step 3: Analysis

The nitro group at the para position stabilizes the phenoxide ion through resonance and inductive effects.

Step 4: Conclusion

Hence, the correct answer is p-nitrophenol.
Final Answer: (C)
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