The Brewster's angle for the air-glass interface is \((54.74)^{\circ }\). If a ray of light going from air to glass strikes at an angle of incidence \(45^{\circ }\), then the angle of refraction is \(\left(\tan (54.74)^{\circ }=\sqrt{2},\,\sin 45=1/\sqrt{2}\right)\)
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Brewster's law gives the refractive index; then apply Snell's law at 45 degrees.