Concept:
The angle subtended at point $A$ by points $P$ and $Q$ is the angle between the vectors $\vec{AP}$ and $\vec{AQ}$. We can find this angle using the dot product formula: $\cos \theta = \frac{\vec{AP} \cdot \vec{AQ}}{|\vec{AP}| |\vec{AQ}|}$.
Step 1: Find the vectors $\vec{AP}$ and $\vec{AQ}$.
Let $A = (1, 2, 3)$, $P = (2, 4, 5)$, and $Q = (3, 3, 1)$.
\[
\vec{AP} = (2-1)\hat{i} + (4-2)\hat{j} + (5-3)\hat{k} = \hat{i} + 2\hat{j} + 2\hat{k}
\]
\[
\vec{AQ} = (3-1)\hat{i} + (3-2)\hat{j} + (1-3)\hat{k} = 2\hat{i} + \hat{j} - 2\hat{k}
\]
Step 2: Calculate the dot product $\vec{AP} \cdot \vec{AQ}$.
\[
\vec{AP} \cdot \vec{AQ} = (1)(2) + (2)(1) + (2)(-2)
\]
\[
\vec{AP} \cdot \vec{AQ} = 2 + 2 - 4 = 0
\]
Step 3: Determine the angle.
Since the dot product is zero, the vectors are perpendicular.
\[
\cos \theta = 0 \quad \Rightarrow \quad \theta = 90^\circ
\]