Question:

Statement I: Arrhenius equation relates reaction rate constants with molar volume distribution.
Statement II: The basis of Arrhenius equation is the activated complex theory of chemical reactions which depends on temperature.
In light of the above statements, choose the most appropriate answer from the options given below:

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Arrhenius equation: k = A e\(^{-E_a/RT}\).
Relates rate constant to temperature and activation energy.
  • Both Statement I and Statement II are correct
  • Both Statement I and Statement II are incorrect
  • Statement I is correct but Statement II is incorrect
  • Statement I is incorrect but Statement II is correct
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the Concept:
Arrhenius equation describes temperature dependence of reaction rates.
It is based on activation energy.

Step 2: Key Formula or Approach:

No specific formula.
Need to understand the Arrhenius equation.

Step 3: Detailed Explanation:

Statement I: Arrhenius equation relates rate constants with molar volume distribution - incorrect.
It relates rate constants with temperature and activation energy.
Statement II: The basis is activated complex theory, dependent on temperature - correct.
Thus, Statement I is incorrect, but Statement II is correct.

Step 4: Final Answer:

Statement I is incorrect but Statement II is correct.
Hence, the correct option is (D).
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