Step 1: Concept
Diffusion is the transport of material by atomic motion within a solid lattice.
Step 2: Meaning
In self-diffusion, atoms of the same type move through the crystal.
Step 3: Analysis
Interstitial diffusion occurs for very small atoms (like Carbon in Iron). In close-packed FCC metals, there is insufficient space for same-sized atoms to move between sites. Movement is only possible when an atom jumps into an adjacent empty lattice site.
Step 4: Conclusion
Consequently, the vacancy mechanism is the dominant mode of self-diffusion in FCC metals.
Final Answer: (D)