Question:

Schottky defect is shown by

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Schottky defect = equal cation and anion vacancies. It is common when ionic sizes are almost similar.
Updated On: Apr 29, 2026
  • Ionic substances in which the size of the cation is smaller than that of the anion
  • Ionic substances in which the cation and anion are of almost similar sizes
  • Ionic substances in which the size of the cation is larger than that of the anion
  • Non-stoichiometric inorganic solids
  • Non-ionic substances
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The Correct Option is B

Solution and Explanation

Concept: Schottky defect is a vacancy defect found in ionic crystals. Equal number of cations and anions are missing from the lattice to maintain electrical neutrality.

Step 1:
Understand Schottky defect.
In Schottky defect: \[ \text{Cation vacancy} + \text{Anion vacancy} \] are formed in equal numbers.

Step 2:
Condition for Schottky defect.
It is common in ionic solids where cation and anion have comparable sizes.

Step 3:
Choose the correct option.
Hence, Schottky defect is shown by ionic substances having cation and anion of almost similar sizes.
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