Question:

$S_{N}1$ reaction is most favoured by:

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$S_{N}1$ reactivity order: $3^\circ > 2^\circ > 1^\circ > \text{Methyl}$.
Updated On: Apr 28, 2026
  • Ethyl bromide
  • 2-methyl-2-bromopropane
  • 2-bromopropane
  • 1-bromopropane
  • 1-bromobutane
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The Correct Option is B

Solution and Explanation

Step 1: Concept
$S_{N}1$ reaction rate depends on the stability of the carbocation intermediate.

Step 2: Meaning

Tertiary ($3^\circ$) carbocations are the most stable due to inductive effects and hyperconjugation.

Step 3: Analysis

2-methyl-2-bromopropane (tert-butyl bromide) forms a $3^\circ$ carbocation. Others are primary or secondary.

Step 4: Conclusion

$S_{N}1$ is most favored by the tertiary halide. Final Answer: (B)
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