Question:

Ratio of wavelengths for \(2\to1\) transition in Li\(^+\), He\(^+\), and H is

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Hydrogen-like atoms $\Rightarrow$ wavelength inversely proportional to \(Z^2\).
Updated On: Apr 23, 2026
  • \(1:2:3\)
  • \(1:4:9\)
  • \(4:9:36\)
  • \(3:2:1\)
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The Correct Option is C

Solution and Explanation

Concept: \[ \lambda \propto \frac{1}{Z^2} \]

Step 1:
Atomic numbers \[ Li^+ = 3,\quad He^+ = 2,\quad H = 1 \]

Step 2:
Ratio \[ \lambda \propto \frac{1}{9} : \frac{1}{4} : 1 \] Multiply by 36: \[ 4 : 9 : 36 \]
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