Step 1: Formula for centripetal acceleration.
The centripetal acceleration \( a_c \) for an electron in the \( n \)-th orbit of a hydrogen atom is given by:
\[
a_c = \frac{v^2}{r} = \frac{k e^2}{m e r^2}
\]
where \( v \) is the speed of the electron, \( r \) is the radius of the orbit, and \( k \) is the Coulomb's constant. The radius of the \( n \)-th orbit is proportional to \( n^2 \), i.e., \( r_n \propto n^2 \).
Step 2: Calculating the ratio.
Thus, the ratio of the centripetal accelerations for the 3rd and 5th orbits is:
\[
\frac{a_{c,3}}{a_{c,5}} = \left( \frac{5}{3} \right)^2 = \frac{625}{81}
\]
Step 3: Conclusion.
Thus, the correct answer is (B) \( \frac{625}{81} \).