Concept:
Multicomponent distillation involves the separation of mixtures based on "key" components (Light Key and Heavy Key). Non-key components are those that are either much lighter or much heavier than the keys.
Step 1: Analyze multicomponent distillation principles.
• Statement A: Correct. In multicomponent systems, non-key components will distribute based on their boiling points relative to the keys; very light non-keys go to the top, and very heavy ones go to the bottom.
• Statement B: Correct. The Underwood equations are the standard analytical method used to calculate the minimum reflux ratio ($R_{min}$) for multicomponent mixtures.
• Statement C: Incorrect. Relative volatility ($\alpha$) typically varies with temperature and composition as the mixture moves through the column. Constant $\alpha$ is a simplifying assumption, not a rule.
• Statement D: Correct. The degree of separation is specified by selecting two "key" components—the Light Key (LK) and the Heavy Key (HK).
Step 2: Final Selection.
Statements A, B, and D are technically sound for distillation design.