Step 1: Recall the function of plasmodesmata.
Plasmodesmata are cytoplasmic connections between adjacent living plant cells.
They facilitate the movement of nutrients and signaling molecules.
Step 2: Identify the correct pair.
Sieve tube elements lack a nucleus and depend on companion cells for metabolic activities.
They are connected through numerous
\[
\boxed{\text{plasmodesmata}.}
\]
Step 3: Choose the correct option.
Hence, plasmodesmata are usually observed between
\[
\boxed{\text{Sieve tubes and companion cells}.}
\]
Therefore, the correct option is
\[
\boxed{(D).}
\]