Step 1: Let the adjacent side vectors be defined.
Let
\[
\vec{u}=5\overline{a}+2\overline{b}
\]
and
\[
\vec{v}=\overline{a}-3\overline{b}
\]
The diagonals of the parallelogram are represented by
\[
\vec{u}+\vec{v}
\]
and
\[
\vec{u}-\vec{v}.
\]
Step 2: Find the first diagonal vector.
\[
\vec{u}+\vec{v}
=
(5\overline{a}+2\overline{b})+(\overline{a}-3\overline{b})
\]
\[
=6\overline{a}-\overline{b}
\]
So, the length of the first diagonal is
\[
|6\overline{a}-\overline{b}|.
\]
Step 3: Find the second diagonal vector.
\[
\vec{u}-\vec{v}
=
(5\overline{a}+2\overline{b})-(\overline{a}-3\overline{b})
\]
\[
=4\overline{a}+5\overline{b}
\]
So, the length of the second diagonal is
\[
|4\overline{a}+5\overline{b}|.
\]
Step 4: Find \(\overline{a}\cdot\overline{b}\).
Given,
\[
|\overline{a}|=2\sqrt{2},\qquad |\overline{b}|=3
\]
and the angle between them is
\[
45^\circ.
\]
Therefore,
\[
\overline{a}\cdot\overline{b}
=
|\overline{a}||\overline{b}|\cos45^\circ
\]
\[
=(2\sqrt{2})(3)\left(\frac{1}{\sqrt{2}}\right)
\]
\[
=6.
\]
Also,
\[
|\overline{a}|^2=(2\sqrt{2})^2=8
\]
and
\[
|\overline{b}|^2=3^2=9.
\]
Step 5: Find \(|6\overline{a}-\overline{b}|\).
\[
|6\overline{a}-\overline{b}|^2
=
36|\overline{a}|^2+|\overline{b}|^2-12(\overline{a}\cdot\overline{b})
\]
\[
=36(8)+9-12(6)
\]
\[
=288+9-72
\]
\[
=225.
\]
Therefore,
\[
|6\overline{a}-\overline{b}|=15.
\]
Step 6: Find \(|4\overline{a}+5\overline{b}|\).
\[
|4\overline{a}+5\overline{b}|^2
=
16|\overline{a}|^2+25|\overline{b}|^2+40(\overline{a}\cdot\overline{b})
\]
\[
=16(8)+25(9)+40(6)
\]
\[
=128+225+240
\]
\[
=593.
\]
Therefore,
\[
|4\overline{a}+5\overline{b}|=\sqrt{593}.
\]
Step 7: Final conclusion.
Thus, the lengths of the diagonals are
\[
\boxed{15,\sqrt{593}}
\]