Question:

Out of the following redox reactions, \[ \text{I. NH}_4\text{NO}_3 \xrightarrow{\Delta} \text{N}_2\text{O} + 2\text{H}_2\text{O} \] \[ \text{II. NH}_4\text{NO}_2 \xrightarrow{\Delta} \text{N}_2 + 2\text{H}_2\text{O} \] \[ \text{III. PCl}_5 \xrightarrow{\Delta} \text{PCl}_3 + \text{Cl}_2 \] Disproportionation is not shown in

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Disproportionation needs same element both oxidized and reduced.
Updated On: Apr 23, 2026
  • I and II
  • II and III
  • I and III
  • I, II and III
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The Correct Option is D

Solution and Explanation

Concept: Disproportionation = same element oxidized and reduced

Step 1:
In reaction I, N has different oxidation states initially.

Step 2:
In reaction II, N again starts with different oxidation states.

Step 3:
In reaction III, P changes but no simultaneous oxidation and reduction of same species.

Step 4:
Hence none are true disproportionation reactions.
Conclusion:
Disproportionation not shown in all (I, II, III)
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