Question:

Osmotic pressure observed when benzoic acid is dissolved in benzene is less than expected. This is because:

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Association reduces particle count and osmotic pressure.
Updated On: Apr 8, 2026
  • benzoic acid is an organic solute
  • benzoic acid has higher molar mass than benzene
  • benzoic acid gets associated in benzene
  • benzoic acid gets dissociated in benzene
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The Correct Option is C

Solution and Explanation

Step 1: Concept
Benzoic acid in benzene exists as a dimer.
Step 2: Analysis

Association leads to a decrease in the number of solute particles.
Step 3: Conclusion

A lower number of particles results in lower observed osmotic pressure.
Final Answer: (C)
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