Step 1: Concept
Molal boiling point elevation constant ($K_b$) is a property of the solvent.
Step 2: Meaning
Water has a very high heat of vaporization due to hydrogen bonding.
Step 3: Analysis
$K_b$ is inversely proportional to the latent heat of vaporization. Water has $K_b \approx 0.52$, which is lower than most organic solvents.
Step 4: Conclusion
Hence, correct answer is water.
Final Answer: (A)