Let's establish the correct matches based on the chemical nature of these plant hormones:
P. Auxin: The primary natural auxin, Indole-3-acetic acid (IAA), is synthesized from the amino acid tryptophan. Thus, P matches with 2.
Q. Gibberellin: Gibberellins are a class of diterpenoid compounds. Their biosynthesis involves pathways that begin with mevalonic acid and lead to the formation of cyclic diterpenes. Thus, Q matches with 4.
R. Ethylene: Ethylene is a plant hormone that is a simple gaseous hydrocarbon with the chemical formula $\text{C}_2\text{H}_4$. Thus, R matches with 1.
S. Abscisic Acid (ABA): Abscisic acid belongs to the class of carotenoids and is chemically a 15-carbon sesquiterpenoid. Thus, S matches with 3.
Therefore, the correct pairings are: P-2, Q-4, R-1, S-3. This corresponds to option (A).
Final Answer: \(\boxed{A}\)