Concept:
This question is based on common ores and their chemical compositions. It is important to memorize standard mineral names and their corresponding chemical formulas.
Step 1: Identify each mineral one by one.
• Sphalerite: This is the chief ore of zinc and has the chemical formula:
\[
\text{ZnS}
\]
So,
\[
(a) \rightarrow (v)
\]
• Malachite: This is a copper ore with characteristic green color and formula:
\[
\text{CuCO}_3 \cdot \text{Cu(OH)}_2
\]
So,
\[
(b) \rightarrow (iv)
\]
• Calamine: This is a zinc carbonate ore:
\[
\text{ZnCO}_3
\]
So,
\[
(c) \rightarrow (ii)
\]
• Cryolite: This is sodium aluminium fluoride:
\[
\text{Na}_3\text{AlF}_6
\]
So,
\[
(d) \rightarrow (iii)
\]
• Siderite: This is iron carbonate:
\[
\text{FeCO}_3
\]
So,
\[
(e) \rightarrow (i)
\]
Step 2: Write final matching.
\[
(a)-(v),\quad (b)-(iv),\quad (c)-(ii),\quad (d)-(iii),\quad (e)-(i)
\]
Step 3: Match with given options.
This corresponds to option (D).
Step 4: Final answer.
\[
\boxed{(D)}
\]