Step 1: Understanding applications of biological materials.
Different biological sources are used for specific purposes in biotechnology and medical science.
Step 2: Correct matching.
Female banded krait venom is used to prepare a DNA probe.
Pancreas from dog was historically used for insulin extraction and purification.
Hair root of human is commonly used as a DNA sample.
{E. coli} is genetically engineered to produce Humulin (human insulin).
Step 3: Conclusion.
Thus, the correct matching is a–iv, b–iii, c–ii, d–i which corresponds to option (D).