Concept:
Plant culture media consist of inorganic salts (macro and micro), carbon sources, vitamins, and solidifying agents.
Step 1: Inorganic Nutrients.
Potassium nitrate ($KNO_3$) (A) provides Nitrogen and Potassium, both of which are needed in large quantities. Therefore, it is a macronutrient (IV). Potassium iodide (KI) (B) provides iodine, which is needed in trace amounts, making it a micronutrient (I).
Step 2: Organic Additives and Support.
Thiamine ($B_1$) (C) is an essential vitamin (III) required by almost all plant cultures for carbohydrate metabolism. Isabgol (D), derived from Plantago ovata husks, is a plant-based mucilage used as an alternative gelling agent (II) to agar for solidifying the medium.
Step 3: Final Matching.
The correct associations result in the sequence A-IV, B-I, C-III, D-II.