
Step 1: Understanding the Concept:
Purification techniques for organic compounds depend on physical properties like boiling point, volatility, and thermal stability.
Step 2: Detailed Explanation:
A. Simple distillation: Used for liquids that are stable at their boiling points and have a large difference in boiling points (typically $>25$ K). (Matches II).
B. Fractional distillation: Used to separate liquids whose boiling points are close to each other, employing a fractionating column. (Matches IV).
C. Steam distillation: Specifically used for substances that are steam volatile and immiscible with water (e.g., aniline). (Matches I).
D. Distillation under reduced pressure (Vacuum Distillation): Used for liquids that have very high boiling points or those that decompose at or below their normal boiling points (e.g., glycerol). (Matches III).
Step 3: Final Answer:
The correct matching is A-II, B-IV, C-I, D-III.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)

Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,