
Step 1: Understanding the Concept:
Purification techniques for organic compounds depend on physical properties like boiling point, volatility, and thermal stability.
Step 2: Detailed Explanation:
A. Simple distillation: Used for liquids that are stable at their boiling points and have a large difference in boiling points (typically $>25$ K). (Matches II).
B. Fractional distillation: Used to separate liquids whose boiling points are close to each other, employing a fractionating column. (Matches IV).
C. Steam distillation: Specifically used for substances that are steam volatile and immiscible with water (e.g., aniline). (Matches I).
D. Distillation under reduced pressure (Vacuum Distillation): Used for liquids that have very high boiling points or those that decompose at or below their normal boiling points (e.g., glycerol). (Matches III).
Step 3: Final Answer:
The correct matching is A-II, B-IV, C-I, D-III.





The figure shows a pipe with cross-section area 10 \( cm^2 \). Water flows from one end with velocity 20 cm/s. The other end of the pipe is closed and consists of 10 holes each of area 30 \( mm^2 \). Find the velocity of water coming out from each hole: 
Which of the following best represents the temperature versus heat supplied graph for water, in the range of \(-20^\circ\text{C}\) to \(120^\circ\text{C}\)? 