Question:

\( \text{SF}_4 \) is isostructural with:

Updated On: Apr 15, 2026
  • C Only
  • C and E Only
  • A and D Only
  • B and E Only
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The Correct Option is C

Solution and Explanation


Step 1: Isostructural Concept.
Two molecules are said to be isostructural when they have the same molecular geometry and bonding patterns.
Step 2: Determine which compounds are isostructural with SF₄.
SF₄ has a seesaw molecular shape due to the presence of one lone pair on the central sulfur atom. Now, let's compare this with the options:
  • (A) BrF₄: This has a square pyramidal structure, different from SF₄.
  • (B) CH₄: This has a tetrahedral structure, different from SF₄.
  • (C) IF₄: This also has a seesaw structure, similar to SF₄, and is isostructural.
  • (D) XeF₄: This has a square planar structure, different from SF₄.
  • (E) XeO₂F₂: This has a different molecular structure, not matching SF₄.
Thus, the correct answer is (C) IF₄, which is isostructural with SF₄.
Final Answer: (C) Only
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