Diagnostic-feature approach: Each soil order in the list is identified by its single most defining diagnostic property.
Ultisols are strongly weathered soils with a clay-enriched subsurface horizon and low base saturation (below 35%). Vertisols contain a high proportion of expanding (smectite) clays, giving them a distinctive shrink-swell behaviour with deep cracks on drying. Mollisols are grassland-derived soils with a thick, dark, organic-matter- and nutrient-rich surface horizon. Alfisols are moderately weathered soils with well-developed horizons and a higher base saturation (above 35%) than Ultisols.
Matching each order to its diagnostic property in this way reproduces the pairing (A)-(III), (B)-(II), (C)-(I), (D)-(IV).