Concept:
Main group elements are those in which the valence electrons occupy s or p orbitals.
\[
\text{s-block: Groups 1 and 2} \quad ; \quad \text{p-block: Groups 13 to 18}
\]
Step 1: Understand classification.
• s-block $\rightarrow$ Group 1, 2
• p-block $\rightarrow$ Group 13–18
• d-block $\rightarrow$ Transition metals
• f-block $\rightarrow$ Inner transition metals
Step 2: Identify main group elements.
Main group = s-block + p-block