Step 1: Use the given relation between \(z\) and \(w\).
Given,
\[
\overline{z}+i\overline{w}=0
\]
Therefore,
\[
\overline{z}=-i\overline{w}
\]
Taking conjugates on both sides,
\[
z=iw
\]
Hence,
\[
w=-iz
\]
Step 2: Express \(zw\) in terms of \(z\).
Substituting \(w=-iz\),
\[
zw=z(-iz)
\]
\[
=-iz^2
\]
Taking arguments,
\[
\operatorname{Arg}(zw)
=
\operatorname{Arg}(-i)+\operatorname{Arg}(z^2)
\]
\[
=-\frac{\pi}{2}+2\operatorname{Arg}(z)
\]
Step 3: Use the condition \(\operatorname{Arg}(zw)=\pi\).
Given,
\[
-\frac{\pi}{2}+2\operatorname{Arg}(z)=\pi
\]
Hence,
\[
2\operatorname{Arg}(z)=\frac{3\pi}{2}
\]
Therefore,
\[
\operatorname{Arg}(z)=\frac{3\pi}{4}
\]
Step 4: Final conclusion.
Thus,
\[
\boxed{\operatorname{Arg}(z)=\frac{3\pi}{4}}
\]