Step 1: We are given:
\[
\bar{z} + i\bar{w} = 0 \quad \text{and} \quad \text{Arg}(zw) = \pi.
\]
Step 2: Take conjugate of both sides:
\[
z - iw = 0 \Rightarrow z = iw.
\]
Step 3: Multiply both sides by \( w \):
\[
zw = iw^2.
\]
Step 4: Using properties of argument:
\[
\text{Arg}(zw) = \text{Arg}(i) + \text{Arg}(w^2) = \frac{\pi}{2} + 2\text{Arg}(w).
\]
Step 5: Given \( \text{Arg}(zw) = \pi \), we get:
\[
\frac{\pi}{2} + 2\text{Arg}(w) = \pi \Rightarrow 2\text{Arg}(w) = \frac{\pi}{2} \Rightarrow \text{Arg}(w) = \frac{\pi}{4}.
\]
Step 6: Since \( z = iw \), then:
\[
\text{Arg}(z) = \text{Arg}(i) + \text{Arg}(w) = \frac{\pi}{2} + \frac{\pi}{4} = \frac{3\pi}{4}.
\]