Step 1: Understand the likelihood function.
The likelihood function for the random sample \( x_1, x_2, x_3, x_4 \) is given by:
\[
L(\theta) = \prod_{i=1}^{4} f(x_i | \theta)
\]
For the given probability density function, the likelihood function is:
\[
L(\theta) = \prod_{i=1}^{4} e^{-\theta x_i} = e^{-\theta (x_1 + x_2 + x_3 + x_4)}
\]
This is valid for \( \theta \leq \min(x_1, x_2, x_3, x_4) \).
Step 2: Maximizing the likelihood function.
To maximize the likelihood, we need to minimize the sum of the observed values. The maximum likelihood estimate of \( \theta \) is \( \min(x_1, x_2, x_3, x_4) \). In this case, \( \theta_{\text{MLE}} = 0.5 \).
Step 3: Estimating \( \theta^2 \).
Thus, the maximum likelihood estimate of \( \theta^2 \) is \( (0.5)^2 = 0.25 \).